Water
Quality in the Great and Little Miami River Basins
Questions you might be asking . . . .
About Great and Little Miami River Basins Study-Unit data
1. What types
of data were collected for the study, and where can I find the data?
3. Are
data available for my stream? How could I find out more?
4. Was
bacteria, septic-system, and sewer information collected for the study?
6. Overall,
is water quality in the Study Unit improving or getting worse?
About human and aquatic-life health
8. What
are the human and aquatic health concerns for nitrate, radon, and arsenic?
12. Why
were algae used to determine the “health” of streams?
14. Is
atrazine a problem in the Study Unit?
About other types of chemicals
20. Why were more volatile organic
compounds (VOCs) found in streams than in ground water?
22. Was there a correlation between
contaminant concentrations in sediment and fish tissue?
23. Why were elevated PCB
concentrations found in fish tissue and not in sediment?
25. What
is NAWQA? How many other NAWQA studies are there and where?
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About Great and Little Miami
River Basins Study-Unit data
1. What types of data were collected for
the study, and where can I find the data?
The types of data
collected are shown on p. 30 (Study Unit Design) of the report “Water Quality
in the Great and Little Miami River Basins, Ohio and Indiana, 1999–2001” (USGS
Circular 1229) (Give web link to report, specifically p. 30). Data can be retrieved from the USGS database,
NWISWeb (National Water Information System-Web) at http://waterdata.usgs.gov/nwis,
the NAWQA Data Warehouse (http://water.usgs.gov/nawqa/sumr/04nr/dataWarehouse.pdf)
at http://water.usgs.gov/nawqa/data,
or in our Water Resources Data, Ohio,
annual reports for 1999–2002.
The information
from NAWQA studies is used by Federal, state and local agencies, tribes,
universities, public interest groups, and the private industry to manage the
Nation's water resources. The information is useful in addressing current
issues, such as the effects of agricultural and urban-land use on water
quality, human health, drinking water, source-water protection, hypoxia, and
excessive growth of algae and plants, pesticide registration, and monitoring
and sampling strategies.
Examples of some
programs the water-quality information is used for include
·
Total Maximum Daily Loads
(TMDLs)
·
Source Water Assessment and Protection (SWAP)
·
Wellhead Protection
·
Best Management Practices (BMPs)
3. Are data available for my stream? How
could I find out more?
Look on the Web at http://oh.water.usgs.gov/, under
“Projects and Programs—The Great and Little Miami River (MIAM) Basins.”
4. Was bacteria, septic-system, and sewer
information collected for the study?
Stream-water
samples at 40 sites were analyzed for the bacteria Escherichia coli (E. coli)
and enterococci. Also, immediately after a large storm from
5. Why doesn’t NAWQA typically use
historical data or data from other agencies?
Were historical data and data from other agencies used in the Great and
Little
NAWQA samples are collected by strict procedures and analyzed with specific methods. The USGS typically does not use water-quality data from other agencies in NAWQA studies because the procedures used to collect samples and methods used to analyze the samples are unknown or different from NAWQA protocols and would limit our ability to compare data from one NAWQA Study Unit to another. For example, raw, untreated water samples are almost always collected by NAWQA studies; however, other agencies often collect and analyze treated water, so the data would not be usable for NAWQA studies.
In this study,
however, existing ecological data were gathered from the Ohio Environmental
Protection Agency (Ohio EPA) Division of Surface Water—Monitoring and
Assessment Section and the Indiana Department of Natural Resources prior to
fish sampling to identify all fish species known or expected to occur in the
Study Unit; such data can be helpful with the identification of problematic
species, new species, or protected species that must be quickly processed and
returned to the stream. This list also provides information in determining what
species should be targeted for fish-tissue analyses. In addition, bed-sediment
and fish-tissue data from state-agency investigations within the Study Unit
were incorporated with NAWQA data to gain a broader perspective of the
occurrence and distribution of contaminants in the
area. Finally, benthic-invertebrate and fish-community data collected by Ohio
EPA at 29 stream sites in the Great and Little Miami River Basins were used to
supplement NAWQA data collected as part of a low-flow study in summer 2001. This synoptic study was designed to assess
the effects of urbanization on stream quality and aquatic-community response.
6. Overall, is water quality in the Study
Unit improving or getting worse?
Because the just completed cycle of study was
the first for the Great and Little Miami River Basins area, we don’t have much
trend information at this point. Continued monitoring of the area over the
coming years will hopefully reveal such trends. From some of our examination of
past data from other sources, however, we can see a couple areas of improvement.
For one, the makeup of the fish community has changed slightly in the past
decade or so in a way that suggests an improvement in water quality; but there
are still far fewer species today than were reported for area streams in the
early days of settlement (More information about fish tissue analyses and
results is available in a report by Stephanie Janosy at http://oh.water.usgs.gov/reports/wrir/wrir02-4305.pdf
). Also noted has been a substantial decrease in phosphorus in the
About human and aquatic-life
health
7. What are the human and aquatic health
concerns for pesticides, volatile organic compounds (VOCs), synthetic organic
compounds (SOCs) and metals in sediment, fish tissue, and/or water?
Contaminants in
sediment are not a direct issue for human health, but they can be an indirect
problem if local fish are accumulating these chemicals via contact with the
sediments or feeding on sediment-dwelling organisms or other fish that have
become contaminated. In places where contamination of fish is a concern,
fish-consumption advisories usually are put into effect. Besides building up in
the bodies of aquatic organisms, these chemicals can directly affect the health
of the organisms. The Canadian sediment guidelines quoted in the summary report
were developed in response to concerns about aquatic-organism health.
Contaminated water
raises similar concerns as contaminated sediment with regard to aquatic
organisms, and aquatic-health-related criteria for water quality have been developed
for some these chemicals (but not all of them). Contaminated water raises
additional concern for human health if the water is used as a drinking-water
supply. Federal and state drinking-water standards are enforced for a wide
variety of these chemicals; but, like for the aquatic-life criteria, not all of
the many possible contaminants have a standard. The drinking-water standards
for
8. What are the human and aquatic health
concerns for nitrate, radon, and arsenic?
These three
contaminants are basically a concern for water as opposed to sediment and for
humans as opposed to other animals. Too much nitrate in drinking water can
result in methemoglobinemia or “blue baby syndrome,” a serious and sometimes
fatal reaction that affects primarily infants and others whose immune systems
are compromised. Radon has been linked to lung cancer, so its presence in water
is a concern largely as a source of release into the indoor atmosphere. Arsenic
in drinking water has been linked to multiple health problems, including
bladder, lung, and skin cancer; cardiovascular disease; diabetes; and
neurological dysfunction. Federal and state drinking-water standards have been
established for all three contaminants.
9. If I am currently being served by a water
company that uses public-supply wells, is my drinking water safe?
The purpose of our
study was to analyze raw, untreated water. Therefore, treated drinking water was
not analyzed in the study (except in a pesticide study in which 21 water
samples were collected before and after treatment from
10. Few of the pesticide breakdown
products, pharmaceuticals, antibiotics, and wastewater compounds
have drinking-water standards or aquatic-life
guidelines associated with them. Does this mean that the water is safe to drink
if these compounds are present?
Currently (2004),
the health implications of trace levels of these chemicals
in our drinking water is largely unknown. Other Federal organizations, such as
the U.S. Environmental Protection Agency and U.S. Department of Health, are
responsible for determining these health issues. The NAWQA program provides
these organizations information about the occurrence and distribution of these
compounds in our Nation’s water supply.
11. How does the presence of all these
contaminants affect the recreational quality of the streams in the Study Unit?
(fishing, canoeing , swimming, etc.)
In many cases,
recreation is unaffected by the chemicals found in the Study Unit because
contact with the water (as opposed to drinking of the water) is not really an
issue. Bacteria and viruses remain the major health-related problem with
water-contact recreation. The bacterial condition of most streams is unknown,
but managers of certain recreation areas along streams may sample the
recreational reach for bacterial quality and issue advisories as necessary.
Synthetic organic chemicals and trace elements can affect the safety of fish
for consumption, so anglers should consult the Ohio EPA at http://www.epa.state.oh.us/dsw/fishadvisory/index.html to see whether a
fish-consumption advisory is in effect for the water body of interest.
12. Why were algae used to determine the
“health” of streams?
Algae are very
sensitive to water chemistry and habitat disturbance, and they have a long
history of being used in water-quality monitoring. They also play an important role in
stream ecosystem functioning, being a source of food and oxygen and providing
habitat to other organisms, such as nonphotosynthetic bacteria, protists,
invertebrates, and fish. Along with fish and benthic invertebrates, algae’s crucial role in stream ecosystems and their excellent indicator
properties make algae a necessary component of environmental studies that
assess human impacts on stream health.
13. Because aquatic-life guidelines have
been exceeded in samples, have there been any physical effects of fish in the
basin?
Aquatic-life
guidelines are established to protect wildlife species from adverse effects
such as mortality, reproductive impairment, and organ damage. In one part of
the study, fish were examined for external deformities, eroded fins, lesions,
and visible tumors (DELT anomalies) during sampling; a weak but significant
correlation was found between these physical symptoms and the benthic
invertebrate pesticide toxicity index (PTI), a composite measure of the
toxicity of pesticides found in a stream-water sample. Also, Ohio EPA has
reported that high nutrient levels in streams in the Great and Little Miami River
Basins were associated with higher rates of DELT anomalies in fish.
14. Is atrazine a problem in the Study
Unit?
As
stated in the report, atrazine is the most heavily applied pesticide to
agricultural lands in the Study Unit and was one of the pesticides most
commonly detected in streams and ground water. However, the detection level of
atrazine used in this study (typically 0.001 microgram per liter (µg/L) or
about 0.001 part per billion) was much lower than the USEPA drinking-water
standard of 3 µg/L for atrazine. With the exception of the storm-runoff study
in the
15. If banned, why was the organochlorine insecticide
dieldrin so commonly detected in fish tissue and bed sediment?
High concentrations
are likely because of dieldrin’s persistence and widespread use in the past,
especially in regions high in corn production.
Dieldrin binds tightly to soil and is stored in fat, so higher
concentrations are found in fish tissue than in water or sediment. Dieldrin is
a byproduct of the insecticide aldrin; therefore, elevated concentrations may
reflect a combination of aldrin and dieldrin residues.
16. Why does this report have so much
written about glyphosate if it was infrequently detected in streams and not
detected in ground water?
Glyphosate is
listed as one of the top 10 herbicides applied to agricultural lands in the
Great and Little Miami River Basins; however, its occurrence within these
basins has not been widely examined until this study. Furthermore, applications
of glyphosate in the Study Unit have continued to increase since the
introduction of glyphosate-tolerant soybeans in 1995. The laboratory method used to detect
glyphosate was still in development at the time of sampling for this study and
had a much higher method detection limit (1.0 micrograms per liter (µg/L)) in
comparison to the other compounds analyzed. Because laboratory methods are now
able to detect glyphosate at lower concentrations, future studies would likely
show a higher number of glyphosate detections in samples collected from this Study
Unit.
Glyphosate
binds to soil and does not dissolve in water as easily as other pesticides. Therefore, it is not found in water
as frequently as other pesticides.
17. Herbicides in streams look to be drastically
high in the
The streams within
the
18. Why is there so much information in the
report about nutrients (nitrogen and phosphorous)? What are the primary sources of nutrients in
the Study Unit?
The term "nutrients" sounds like a
good thing. Unfortunately, elevated concentrations of nutrients (nitrogen and
phosphorus) in streams can have substantial environmental and economic
consequences, in addition to human health concerns. Ingestion of drinking water
with high nitrate concentrations can cause low oxygen levels in the blood of
infants, a potentially fatal condition known as methemoglobinemia, or “blue
baby syndrome.” Because of these health concerns, the U.S. Environmental
Protection Agency (USEPA) set the drinking-water standard for nitrate at 10
milligrams per liter.
Elevated nutrient concentrations can lead to
excessive and unsightly growth of algae and other aquatic plants, which can
clog water-intake pipes and filters and can interfere with recreational
activities such as fishing, swimming, and boating. The decay of plants often
results in foul odors, bad taste, and low dissolved oxygen concentrations in
water (or hypoxia, which can cause fish kills).
Excessive growth of algae was found in some
large streams with elevated nutrients and very little shade in the Great and
Little Miami River Basins.
Streams draining agricultural land in the
Great and Little Miami River Basins had the highest average concentration of
nitrogen, whereas streams draining a mix of land uses had the highest average
concentration of phosphorus. Runoff of commercial fertilizer and manure applied
to agricultural lands is a major source of nitrogen to area streams, whereas
wastewater-treatment discharges at
Confined animal feeding operations (CAFOs),
mainly for poultry and swine, are concentrated in the northwestern part of the
Study Unit, mostly in the
Nitrate concentrations in 10 of 104
ground-water samples exceeded the USEPA drinking-water standard of 10
milligrams per liter, or about 10 parts per million. Concentrations of nitrate
in water from shallow monitoring wells in agricultural areas were the highest
among area wells and among the highest in the Nation as sampled by the USGS
NAWQA Program.
About other types of chemicals
19. Why is information in the report
on synthetic organic compounds (SOCs), semivolatile organic compounds (SVOCs),
and volatile organic compounds (VOCs) presented separately if they are all
organic compounds?
SOCs are synthetic
organic compounds that are sometimes further distinguished on the basis of
their chemical and physical properties. Because of these differences in
chemical and physical properties, they behave differently in the environment:
some kinds of organic compounds can be found most readily in water samples,
whereas others are typically found in sediments and fish tissue. Also, the
sources of organic compounds differ, some being commonly associated with pest
control and others with industrial processes. Details about the various
subdivisions of organic chemicals can be found here.
20. Why are more volatile organic
compounds (VOCs) found in streams than in ground water?
VOCs in ground
water may be breaking down to carbon dioxide and water in the reducing
environment in the aquifer. In addition, results could reflect sampling
conditions, including periods of unusually heavy or light rain, and site
proximity to residential and commercial land use.
21. Why were many of the organic compounds
detected in fish and streambed sediment not examined in the water samples?
These organic
compounds were not examined in the water samples because they are not very
soluble in water. Commonly, the organic compounds soluble in water are not
soluble in fat (fish) or do not bind to sediment and vice versa.
22. Was there a correlation between
contaminant concentrations in sediment and fish tissue?
Relations between
sediment and tissue concentrations are difficult to determine and were not
attempted because of the many factors that affect the behavior, fate, and
transport of trace elements and synthetic organic chemicals, including chemical
speciation, water characteristics, physical features (such as dams),
antagonistic effects, and adsorption and desorption rates. Fish species,
migration, feeding preferences, metabolic rates and lipid (fat) content also
must be taken into consideration.
Instead, sediment
and tissue data from USGS, Ohio EPA, and Indiana Department of Environmental
Management were compared to sediment-quality guidelines and fish-tissue
guidelines to identify compounds that exceed published limits and, by means of
occurrence and distribution maps, to identify areas that may be a concern for
wildlife health. No distinct geographic overlap between sediment and fish-tissue
sites was evident with respect to elevated organochlorine insecticide
concentrations or PCBs. (More information about fish tissue and sediment
analyses and results is available in a report by Stephanie Janosy at http://oh.water.usgs.gov/reports/wrir/wrir02-4305.pdf
).
23. Why were elevated PCB concentrations
found in fish tissue and not in sediment?
Fish are repeatedly
exposed to contamination through different routes, including direct contact
with contaminated sediment and consumption of contaminated plant or animal
material. PCBs biomagnify, meaning they increase in concentration
at higher levels in the food chain (for example, predators at the top of the
food chain will have the highest levels, especially older fish). Two
important factors contribute to the high detection of PCBs in the Study Unit: PCBs
are hydrophobic (not very soluble in water) and strongly lipophilic (have an
affinity for lipids, or fats). PCB concentrations can be fairly high in
sediments that are high in organic-matter or clay content.
24. You say that further investigation of
arsenic in the buried valley aquifer is warranted. Is any investigation actually being done?
Further research on factors controlling arsenic in ground water is
being
conducted in Preble,
25. What is NAWQA? How many other NAWQA
studies are there and where?
NAWQA is an acronym for National
Water-Quality Assessment. NAWQA is a National program in which USGS scientists
collect and interpret data about water chemistry, hydrology, land use, stream
habitat, and aquatic life in more than 50 river basins and aquifer systems
(called Study Units) covering all 50 states. Because the same sample-collection
procedures and methods are used in each Study Unit, water-quality results in
different states, regions, land-use settings, ecoregions, and aquifer types
across the Nation can be compared. Data from the NAWQA studies are used by
local, state, and Federal agencies to manage our Nation’s water resources. More information about the NAWQA program and
specific Study Units are at http://water.usgs.gov/nawqa/.
26. How does this study differ from those conducted
by other agencies and universities in
Unlike many studies by state agencies and
universities, NAWQA studies are part of a nationwide reconnaissance in which
many target constituents and study methods are similar or identical. Because
the all the Study Units have the same approach in common, current and future
researchers have the opportunity for comparing the effects of various land-use
settings on water quality without worrying whether differences in methodology
are confounding differences they see in the data. NAWQA will also go a long way
in helping us understanding water quality at national scale. The ability to
integrate local and national scales of data collection and analysis is a unique
feature of the USGS NAWQA Program. Additional
information can be found here.
In 2001, the Great
and Little Miami River Basin Study Unit was combined with the White River Study
Unit in
In
NAWQA Cycle II studies, emphasis is placed on describing long-term trends, and
understanding human and natural factors that control water quality. Long-term
trends are studied by resampling stream and well sites established in Cycle I.
These sites are part of the Trend Networks for Streams and Ground Water. The
Effects of Land-Use Change on Water Quality Program looks more directly at
effects of urbanization and agricultural management practices on water quality.
Factors that control water quality are addressed with Topical Studies that not
only focus on sources, transport processes, and effects but also address
implications for water-quality management. The