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Pharmaceuticals And Other Emerging Contaminants In Water
Although
referred to as "emerging contaminants," many of these compounds were or have
been in use for a long time and so their presence in water is not new. What is
new; however, is our ability to effectively measure these contaminants at the
very low concentrations that typically are found in surface and ground water, as
well as the realization that some of the compounds are not removed by
conventional wastewater and potable-water treatments. While adverse effects on
aquatic organisms or humans have been documented for some of these compounds,
the effects of long-term exposure to many of the compounds is not known,
particularly since they can be present in complex mixtures.
Many studies of emerging contaminants have been done
by the U.S. Geological Survey
Toxic Substances Hydrology
Program. In
one national study, one or
more of these contaminants were found in 80 percent of the 139 streams sampled
in 30 states across the U.S.
In a regional USGS study in the
Great and Little Miami Basins,
the presence of emerging contaminants in Ohio waters
was documented.
Of the 116 contaminants targeted during the
study, 61 were detected at least once. Contaminants were present more frequently
in surface-water than in ground-water samples.
New analytical
methods have enabled
researchers to better assess the presence of emerging contaminants in waters and
sediments. These methods presently are being used to assess waters for two
separate studies in Ohio described below.
The Occurrence of Organic Wastewater
Compounds in the Tinkers Creek Watershed in Northeast Ohio
In
cooperation with Ohio Water Development Authority, City of Solon, City of
Bedford, City of Twinsburg, Portage County, City of Bedford Heights, Summit
County, National Park Service, and Ohio EPA.
The U.S. Geological Survey is investigating the occurrence of antibiotics,
pharmaceuticals, personal-care products, and other organic wastewater compounds
(OWCs) entering the Tinkers Creek watershed and selected other tributaries to
the Cuyahoga River in northeast Ohio. The Tinkers Creek watershed was chosen as
a study basin after biological surveys indicated that the fish population was
not exploiting the available stream habitat, yet conventional water-quality data
did not explain that phenomenon. Because effluent from wastewater-treatment
plants constitutes a continuous and sometimes large portion of the flow in
Tinkers Creek and its tributaries, there was concern that contaminants in
wastewater may have contributed to the impairment of the fish population.
However, no data were available on the occurrence or distribution of OWCs in the
Tinkers Creek watershed that could support or refute that concern.
The overall goal of the project is to investigate the presence and distribution
of a variety of common OWCs in the Tinkers Creek watershed. The study focuses
primarily on identifying the presence of OWCs in receiving waters near
wastewater-treatment plant outfalls.
The presence and distribution of OWCs is being assessed by analyzing streambed
sediments and media from passive-sampling devices that were deployed in the
watershed over a 28-day period. The passive-sampling devices include two types
of polar organic chemical integrative samplers (POCIS) and a semipermeable
membrane device (SPMD). The different media contained in the passive-sampling
devices are designed to sample and concentrate different classes of compounds in
a fashion that provides a time-weighted measure of concentration.
This project is ongoing and a full report is expected by summer 2008. For more
information regarding this project, contact John Tertuliani at
tertulia@usgs.gov
or (614) 430-7778.
Antibiotics and Wastewater Compounds in Source and Finished Drinking Water
from the Upper Scioto River Basin, Central Ohio
(In cooperation with
the City of Columbus, Division of Power and Water.)
As
a result of recent attention on the issue of emerging contaminants in public
water supplies, the City of Columbus, Ohio, has received inquiries regarding the
presence of antibiotics, pharmaceuticals, and other wastewater compounds in City
water supplies. A national reconnaissance study completed during 1999-2000
revealed that a variety of compounds including antimicrobials, detergents,
disinfectants, fragrances, fire retardants, prescription and non-prescription
drugs, can enter streams and ground water. These wastewater compounds can be
released into the environment by wastewater-treatment plants (WWTPs), animal
feed lots (AFOs), discharges from industrial facilities, septic disposal
systems, or from land application of sludge, biosolids, or animal waste. Little
is known about the occurrence, fate, or transport of these compounds and the
possible health effects linked to human and aquatic life. Some of these
compounds are endocrine disruptors and have been linked to negative hormonal and
toxic effects in aquatic organisms; others are suspected of increasing
antibiotic resistance in bacteria in the environment.
Eighty-five percent of the City’s annual water supply (roughly 27
billion gallons of water) is drawn from three reservoirs in the Upper Scioto
River Basin. This portion of the basin contains several large WWTPs and AFOs
that discharge into the Scioto River. On the basis of previous studies and the
belief that wastewater contaminants are derived from both urban and agricultural
sources (including treated sewage effluent and runoff from AFOs), the potential
exists for wastewater contaminants to be present in source waters in the Basin
used to supply drinking waters to residents.
The objectives of this project are to determine the occurrence and
concentration of antibiotics and wastewater compounds in source waters from the
Upper Scioto River Basin, and determine if antibiotics and wastewater compounds
are present in drinking-water supplies before and after treatment.
The study includes the following:
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Depth- and width-integrated stream samples collected from the
following locations: Powder Lick near Somersville, Mill Creek below
Marysville, Scioto River near Prospect, Big Walnut Creek at Sunbury, and the
Scioto River adjacent to the Columbus Well-104.
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Paired source and finished drinking water samples collected at
three City of Columbus Water Treatment Plants: Dublin Road, Hap Cremean, and
Parsons Avenue.
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A ground-water sample collected from a production well at the
Columbus South Well field.
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Samples were collected during or immediately after rainfall
events in an effort to target periods before, during, and after application
of manure in the watershed. In addition, low-flow samples were collected in
late summer when treated wastewater and septic tank discharge are thought to
represent a larger proportion of the total streamflow than during periods of
higher flow.
-
Samples were analyzed for 49 antibiotics by the Organic
Geochemistry Research Lab in Lawrence Kansas, and 59 wastewater compounds by
the National Water Quality Lab in Denver, Co.
This project is ongoing and a full report is expected by summer
2008. For more information regarding this project, contact Dennis Finnegan at
dpfinneg@usgs.gov or (614) 430-7731.
More information regarding emerging contaminants and other USGS projects can
be obtained by contacting Greg Koltun at gfkolton@usgs.gov or (614) 430-7708. |